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W1A/ POE-g-MAH serious maleic anhydride grafted POE used as compatibilizer coupling agent for Polyamides/ Nylon/PA glass fiber

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Model No.: W1A
lntroduction:

W1A is prepared by grafting maleic anhydride by POE reaction. Since it introduces a strongly polar side group (maleic anhydride) on the main chain of POE molecule, maleic anhydride grafted POE can become a polar material. A bridge for adhesion and compatibility with non-polar materials


W1A is prepared by grafting maleic anhydride by POE reaction. Since it introduces a strongly polar side group (maleic anhydride) on the main chain of POE molecule, maleic anhydride grafted POE can become a polar material. A bridge for adhesion and compatibility with non-polar materials. In the application of nylon + glass fiber modification, it can react with the glass fiber after surface treatment to improve the compatibility of nylon and glass fiber, thereby improving the tensile strength and impact strength of nylon. W1A can be used as both a compatibilizer and a toughening agent. As a nylon compatibilizer, it is also suitable for PA/PE and PA/PP alloys, which can improve the toughness of the alloy. As a nylon toughening agent, its low temperature The performance is very superior, the impact strength of PA6+15%W1A at -40℃ can be maintained at 35-40% of the impact at room temperature.


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Description

W1A is prepared by grafting maleic anhydride by POE reaction. Since it introduces a strongly polar side group (maleic anhydride) on the main chain of POE molecule, maleic anhydride grafted POE can become a polar material. A bridge for adhesion and compatibility with non-polar materials. In the application of nylon + glass fiber modification, it can react with the glass fiber after surface treatment to improve the compatibility of nylon and glass fiber, thereby improving the tensile strength and impact strength of nylon. W1A can be used as both a compatibilizer and a toughening agent. As a nylon compatibilizer, it is also suitable for PA/PE and PA/PP alloys, which can improve the toughness of the alloy. As a nylon toughening agent, its low temperature The performance is very superior, the impact strength of PA6+15%W1A at -40ºC can be maintained at 35-40% of the impact at room temperature.

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Typical application:

1. Nylon toughening reinforcement
2. Nylon composite filling
3. Nylon, polypropylene, polyethylene mixed with gold compatibilizer

ProductAppearanceMelt index
(190ºC,2.16kg):g/10min
Grafting ratioDensity(g/)
W1A
 
White or light yellow even granules0.5-1.5high0.87
Features: This produce is ethylene elastomer with functionalized maleic anhydride,which is especially suitable for super-tough or cold-resistant nylon.
Application:
  1. Be used for PA6 or PA66 compatibilizing or toughening. Increase the impact resistance and processability of nylon,decrease the water absorption,greatly improve the cold-resistance.
  2. Be used for the compatibilizer of nylon and polypropylene/polyethylene alloy.
  3. Be used for the macromolecular modifier(couling agent)of mineral-filled or grass-flber-filled nylon.

3Reaction principle


POE is a random copolymer elastomer of ethylene and high-carbon α-olefins (1-butene, 1-hexene, 1-octene, etc.) catalyzed by metallocene catalysts. It has excellent mechanical properties, rheological properties and UV light resistance. In addition, POE also has the advantages of good affinity with polyolefins and good low temperature toughness, and is widely used in the toughening and modification of non-polar polymers such as polypropylene (PP) and polyethylene (PE).

POE is a non-polar elastomer with poor compatibility with polar materials, which is not conducive to the modification and reinforcement of polar polymers such as polyamide (PA) and polyethylene terephthalate (PET). The common practice is to first carry out graft modification on POE, and graft low molecular weight compounds containing polar functional groups on the macromolecules, thereby changing the polarity of the POE molecular chain and improving its compatibility with polar polymers. , so that it can be applied to the modification of polar polymers. Commonly used grafting monomers for POE are maleic anhydride (MAH), glycidyl methacrylate (GMA), methacrylic acid (MAA), acrylic acid (AA) and the like.

POE-g-MAH (POE grafted maleic anhydride) is obtained by grafting highly reactive maleic anhydride (MAH) monomer by reactive extrusion with POE elastomer as matrix. POE-g-MAH can be used as a good toughening agent and compatibilizer. Its toughening effect is better than that of pure POE without grafting. It is suitable for PA, PP, PE, PC, ABS, PET, PBT, etc. Compatibility and toughening of its alloy materials.



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Company Profile

Coace Chemical Company Limited is located in Xiamen Special Economic Zone, China. It is a national high-tech enterprise integrating R&D, production and sales of polymer materials, specializing in R&D, production, sales and service of plastic compatibilizers and toughening agents.

For more than ten years, the company has been adhering to the business philosophy of "stable quality, refinement and globalization", serving the market, the factory owns 50,000 square-meter area and nearly 100 employees, including 20 technical R&D personnel, and is equipped with eight modern extruding-pellets systems production lines, which ensure the annual capacity of ten thousand metric tons. The products cover compatibilizers, coupling agents, impact modifiers, and other functional additives. and obtained ISO9001 quality management certification, with an annual production capacity of 20,000 tons.

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Characterisitic

Product models

W1A

W1A-2

Melting index

0.3-1.0

0.3-1.0

Grafting rate

High

High

density

0.87g/cm³

0.87g/cm³

performance

PA reinforced filling, ultra-low temperature toughening

PA reinforced filling, ultra-low temperature toughening

Typical applicationadvantages

Application:

1.Be used for PA6 or PA66 compatibilizing or toughening. Increase the impact resistance and processability of nylon,decrease the water absorption,greatly improve the cold-resistance.

2.Be used for the compatibilizer of nylon and polypropylene/polyethylene alloy.

3.Be used for the macromolecular modifier(couling agent)of mineral-filled or grass-flber-filled nylon.

Application:

1.Be used for PA6 or PA66 compatibilizing or toughening. Increase the impact resistance and processability of nylon,decrease the water absorption,greatly improve the cold-resistance.

2.Be used for the compatibilizer of nylon and polypropylene/polyethylene alloy.

3.Be used for the macromolecular modifier(couling agent)of mineral-filled or grass-flber-filled nylon.


Applications
PerformanceUnitPA66PA6+30%GF+6%W1A
Tensile strengthMPa
75
150
Flexural strengthMPa
102
215
Lzod notched impact strength(23℃)J/m
80
200

Note:The above data are typical experimental values, for reference only, the viscosity of PA6 used in Table 3 is 2.8, and the viscosity of PA66 used in Table 4 is 2.7

Note:The data above are all experimental typical values, only for reference .

Suggested dose: The dose (5-25%) may be increased or decreased properly according to the toughness requirements and by taking the cost into consideration.3-10% shall be adopted for PA6/PA66 reinforcing and toughening, while 5% shall be adopted for the compatibilizer of nylon and polypropylene/polyethylene alloy.

Packaging, storage and transportation: 20kg kraft bag with internal plastic bag. This product shall be treated as non-hazardous article and be stored or transported under dry conditions, and sunlight and rain shall be avoided.


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